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Molecular Microbiology, 51 (2), 437446

For topical or in vivo investigational use, concentrations of 0.05% to 0.1% (w/v) have been employed in wound-healing studies without reported adverse events

As outlined in the Figure above the pathway of melatonin synthesis from serotonin involves two reactions

J Biol Chem 277:43536 Hashimoto W, Suzuki H, Nohara S, Tachi H, Yamamoto K, Kumagai H (1995) Subunit association of gamma-glutamyltranspeptidase of Escherichia coli K-12