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This is most likely attributed to the inability of the constrained 13- and 14-membered macrocycles to adopt the proper transition states required for cleavage of the N-terminal peptide bond (Andersson et al., 2011) (Figure 8)

In vitro studies have demonstrated that black garlic extract can protect against oxidative stress, inflammation, and endothelial dysfunction, all of which are involved in the development of CVDs [66, 68]

Glutathione is commonly found in two forms: reduced glutathione (GSH) and oxidized glutathione (GSSH)

This pairing has become a reference point in discussions about optimized hormone signaling

& Woodward, L

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