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A second, more subtle reason is that the sp3 hybridized carbon on the ring junction (adjacent to the nitrogen) imparts a slight pucker to the nitrogen, so that orbital overlap is even more difficult than in a linear amide

15 The difference in half-life explains why liraglutide must be injected daily, while semaglutide can be taken only once a week

They just live, enjoy the world and leave the world the way it was when they came in

Toxicon 193, 2127

Protein Peptide Lett 15(4):320326 [DOI] [PubMed] [Google Scholar] Koleva AI, Petkova-Yankova NI, Nikolova RD (2019) Synthesis and chemical properties of 3-phosphono-coumarins and 1,2-benzoxaphosphorins as precursors for bioactive compounds

doi: 10.1002/ajh.25882 23 GrantW