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MELATONIN - BIOSYNTHESIS, METABOLISM, AND PHARMACOKINETICS Endogenous small molecule MEL is synthesized in pinealocytes and other tissues as the end product of the metabolic pathway in which tryptophan, after being transported into the cell, is further transformed by enzymes such as tryptophan hydroxylase (TPH), aromatic amino acid decarboxylase (AAAD), serotonin N-acetyltransferase (SNAT, aralkylamine N-acetyltransferase- AANAT) and N-acetylserotonin O-methyltransferase (ASMT) (16)

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