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At high concentrations of ROS, lipids, especially PUFAs, are oxidatively damaged, causing lipid peroxidation and inducing ferroptosis

Fundamentals of redox regulation in biology

Food and Drug Administration) Dosage and infusion rate : high doses or rapid infusion increase risk of systemic reactions (allergy, shock, organ stress)

NAPQI, N-acetyl-p-benzoquinone imine

Role of roasting conditions in the level of chlorogenic acid content in coffee beans: correlation with coffee acidity

Both have a place, but they are not interchangeable, and neither is a substitute for addressing an underlying medical cause when one exists