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Indeed, in the first report that demonstrated a significant role of ceramide in erythrocyte death pathways, it has been ruled out that the elevated ceramide levels originate from the biosynthetic pathway [122]

The acidic pH from ascorbic acid disrupts the copper-peptide bond

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10.1097/cm9.0000000000000627 55 YaoJ.ZhaoL.ZhaoQ.ZhaoY.SunY.ZhangY.et al (2014)

This creates a direct pathway from NAD+ availability to antioxidant defense